Saturday, November 30, 2019

Software That Helps Small Biz Owners Use Social Media To Stay Connected With Clients - The Writers For Hire

SOFTWARE THAT HELPS SMALL BIZ OWNERS USE SOCIAL MEDIA TO STAY CONNECTED WITH CLIENTS Created by Sean and Wintress Odom, Socialot is web-based software built specifically for small-business owners who are struggling to efficiently use social media to engage their customers. Sean Odom notes, You dont have to be a social media marketing guru to use it. You dont even need a marketing department. All you need is a computer and an Internet connection. The software is unique in the marketplace because it helps business owners use social media to stay connected with clients even if these owners know little to nothing about social media. The inspiration for Socialot came directly from small business owners. We knew we could use social media to connect with customers, but it was difficult to find time to do it efficiently, says Wintress. We wanted a way to centralize our activities and quickly use social media for lead follow up, marketing, and branding then move on with our daily activities. Socialot provides several tools that allow social media novices to leverage social media. Users can: Keep engaged with clients through a contact/lead management system featuring a social media interface. Monitor the Internet for mentions of their company name (such as reviews or news). Share promotions, news releases, messages, pictures, or videos to multiple social media sites at once. Schedule posts to Facebook, Twitter, LinkedIn days or months in advance. Share positive reviews across multiple social media sites. Socialot gives business owners a quick and easy way to manage multiple social media accounts such as Twitter, LinkedIn, Facebook, Flickr, and YouTube from a single site. With one click, a small-business owner can post updates, share news, and monitor their online business reputation. A flagship feature is Socialots Contact Management System (CMS) with built-in social features. Socialots CMS has many of the features of a standard CMS: keeping track of follow-up notes and allowing a business owner to set follow-up reminders, for example. Yet, the system also integrates social media. This feature makes it easy for owners to use social networking sites for individualized promotions or friendly touch points. Socialot lets you stay in touch with past, current, and potential customers in a non-salesy way, says Wintress. Say you havent heard from a past client in a while and you just want to remind him that youre out there. Or you made contact with a prospect a few weeks ago. A call or email might seem like youre fishing for a sale. But if you use Socialot to like his Facebook post or comment on his Twitter feed youre connecting without being pushy. Its a great way to follow up without really following up.' Other Socialot features provide more ways to keep owners in touch with clients and prospects on a daily basis. Call for information. Socialot.com goes live on July 17, 2012. For more information about Socialot.com, please contact Wintress Odom at [emailprotected]

Tuesday, November 26, 2019

Syrian President Bashar al-Assad - Profile

Syrian President Bashar al-Assad - Profile Why Bashar al-Assad Matters: Syrias Hafez al-Assad, in power since June 10, 2000, is one of the Middle Easts most ruthless, autocratic, minority rulers in one of the worlds most closed societies. Assad also maintains Syrias pivotal role on the Middle Easts strategic map: He is an ally of Irans Shiite theocracy, he supports and arms Hamas in the Gaza Strip, as well as Hezbollah in Lebanon, thus maintaining a level of enmity toward Israel that so far has precluded peace: Israel has occupied Syrias Golan Heights since the 1967 war. Presumed a reformer when he took Power, Bashar al-Assad has proved no less repressive than his father. Bashar al-Assads Early Life: Bashar al-Assad was born on Sept. 11, 1965, in Damascus, the Syrian capital, the second son of Hafez al-Assad (1930-2000), who had tyrannically ruled Syria since 1971, and Anisa Makhlouf Bashar. He had three brothers and a sister. He spent years training as an eye doctor, first at a military hospital in Damascus then in London, at St. Marys Hospital. He was not being groomed for the presidency: his oldest brother Basil was. In January 1994, Basil, who led Syrias presidential guard, died in a car crash in Damascus. Bashar was immediately and unexpectedly thrust into the limelightand the succession line. Bashar al-Assads Personality: Bashar al-Assad was not groomed to be a leader. Where his brother Basil was gregarious, outgoing, charismatic, arrogant, Dr. Assad, as he was referred to for a while, was retiring, shy, and appearing to have few of his fathers wiles or will to poweror ruthlessness. Friends admit, The Economist wrote in June 2000, that he cuts a rather meek and awkward figure, unlikely to inspire the same terror and admiration as his handsome, athletic, outgoing and ruthless brother. Basil was the gangster type, says one Syrian. Bashar is much more quiet and thoughtful. Early Years of Power: Bashar al-Assad had been running a private medical practice. But when his brother died, his father summoned him from London, sent him to a military academy north of Damascus, and started preparing him for the reins of power- which he took when Hafez al-Assad died on June 10, 2000. Bashar has gradually turned into a younger version of his father. I have a lot of respect for experience, Bashar al-Assad said just as he was taking power, and I am going to try always to acquire it. Hes lived up to that pledge. He suggested that hd relax Syrias repressive police state, even explore political reforms. He barely did. Toying With the United States and Israel: Almost from the beginning of Bashar al-Assad reign, theres been a yo-yo effect in his relations with the United States and Israelimplying engagement during one phase only to retreat into intransigence and extremism the next. Whether its a strategy or a lack of self-confidence might seem unclear until the approach is seen in the context of how Bashars father maintained power: not by innovating, not by daring, but by keeping the opposition off balance, by undermining expectations rather than living up to them. Theres been a see-saw effect on two fronts since 2000, without as yet producing lasting results. Bashar al-Assads See-Saw: Cooperation With the U.S.: Shortly after the 2001 terrorist attacks on the World Trade Center and the Pentagon, Assad proved to be a relatively reliable ally in the fight against al-Qaeda, cooperating with U.S. intelligence and, in more sinister ways, lending his prisons to the Bush administrations rendition program. It was in Assads prisons that Canadian national Maher Arar was tortured, at the administrations behest, even after Mahar was found to be innocent of any ties to terrorism. Assads cooperation, like Muammar el-Qaddafis,was not out of appreciation for the west but out of fear that al-Qaeda would undermine his regime. Bashar al-Assads See-Saw: Talks With Israel: Assad has similarly see-sawed with Israel over peace talks and the resolution of the Golan Heights occupation. In late 2003, Assad, in an interview with The New York Times, appeared ready to negotiate: Some people say there are Syrian conditions, and my answer is no; we dont have Syrian conditions. What Syria says is this: negotiations should be resumed from the point at which they had stopped simply because we have achieved a great deal in these negotiations. If we dont say this, it means we want to go back to point zero in the peace process. But similar suggestions were made over subsequent years, to no end. Syrias Nuclear Reactor: In September 2007, Israel bombed a remote area of northeast Syria, along the Euphrates River, where, Israel and the United States alleged, North Korea was helping Syria build a plutonium-based nuclear plant that would have been capable of producing nuclear weapons. Syria denied the allegations. Writing in The New Yorker in February 2008, investigative reporter Seymour Hersh said the evidence was circumstantial but seemingly damning. But Hersh raised serious doubt about the certainty that it was a nuclear reactor, even though he conceded that Syria was cooperating with North Korea on something military. Bashar al-Assad and Reform: As with his stance toward Israel and the United States, Bashar al-Assads promises of reform have been many, but his retreats from those promises have been just as frequent. Theres been a few Syrian springs where dissenters and human rights advocates were given a longer leash. But those brief springs never lasted. Assads promises of local elections have not been followed through, though financial restrictions on the economy were lifted early in his reign and helped the Syrian economy grow faster. In 2007, Assad held a sham referendum extending his presidency seven years. Bashar al-Assad and Arab Revolutions: As of early 2011, Bashar al-Assad was firmly planted on Middle Eastern soil as one of the regions most ruthless tyrants. He brought Syrias 29-year occupation of Lebanon to an end in 2005, but only after the likely Syrian- and Hezbollah-backed assassination of Lebanese Prime Minister Rafik Hariri triggered the Cedar Revolution on Lebanons streets and drove the Syrian army out. Syria has since reasserted its power over Lebanon, re-infiltrating the countrys intelligence services and, ultimately, reasserting Syrian hegemony when Hezbollah brought the government down and brokered its re-institution, with Hezbollah at the helm. Assad is not merely a tyrant. Like Bahrains Al Khalifa ruling family, which is Sunni and ruling, illegitimately, over a majority of Shiites, Assad is an Alawite, a break-away Shiite sect. Barely 6 percent of Syrias population is Alawite. The majority is Sunni, with Kurds, Shiites and Christians forming minorities of their own. In an interview with the Wall Street Journal in January 2011, Assad said downplayed the risks of revolution in his country: I am not talking here on behalf of the Tunisians or the Egyptians. I am talking on behalf of the Syrians, he said. It is something we always adopt. We have more difficult circumstances than most of the Arab countries but in spite of that Syria is stable. Why? Because you have to be very closely linked to the beliefs of the people. This is the core issue. When there is divergence between your policy and the peoples beliefs and interests, you will have this vacuum that creates disturbance. Assads certainties were soon proven wrong as disturbances erupted in various parts of the countryand Assad assaulted them with his police and military, murdering many protesters, arresting hundreds, and silencing Internet communications that have helped organize protests across the Middle East. In short, Assad is a flirt, not a statesman, a tease, not a visionary. Its worked so far. Its not likely to work for ever.

Friday, November 22, 2019

Definition and Examples of Euro-English

Definition and Examples of Euro-English Euro-English is an emerging variety of the English language used by speakers in the European Union whose mother tongue is not English. Gnutzmann et al. point out that it is not clear, as yet, whether English in Europe will in the foreseeable future become a language in its own right, one that is owned by its multilingual speakers, or whether the orientation towards native-speaker language norms will continue to persist (Communicating Across Europe in  Attitudes Towards English in Europe, 2015). Observations Two foreign girlsnannies? tourists?one German, one Belgian (?), talking in English beside me on the next table, unconcerned by my drinking and my proximity. . . . These girls are the new internationalists, roving the world, speaking good but accented English to each other, a kind of flawless Euro-English: I am very bad with separation, the German girl says as she stands up to leave. No true English speaker would express the idea in this way, but it is perfectly comprehensible. (William Boyd, Notebook No. 9. The Guardian, July 17, 2004)   The Forces Shaping Euro-English [T]he evidence is accumulating that a Euro-English is growing. It is being shaped by two forces, one top-down and the other bottom-up.The top-down force comes from the rules and regulations of the European Union. There is an influential English Style Guide issued by the European Commission. This makes recommendations about how English should be written in official documents from the member states. On the whole it follows standard British English usage, but in cases where British English has alternatives, it makes decisionssuch as recommending the spelling judgment, not judgement...More important than these top-down linguistic pressures, I suspect, are the bottom-up trends which can be heard around Europe these days. Ordinary Europeans who have to use English to each other every day are voting with their mouths and developing their own preferences. . . . In sociolinguistics, the technical term for this interaction is accommodation. People who get on with each other find that their acc ents move closer together. They accommodate to each other...I dont think Euro-English exists yet, as a variety comparable to American English or Indian English or Singlish. But the seeds are there. It will take time. The new Europe is still an infant, linguistically. (David Crystal, By Hook or by Crook: A Journey in Search of English. Overlook, 2008) Characteristics of Euro-English [I]n  2012 a report found that 38% of the EU’s citizens speak [English] as a foreign language. Nearly all of those working at EU institutions in Brussels do. What would happen to English without the English? A sort of Euro-English, influenced by foreign languages, is already in use. Many Europeans use control to mean monitor because  contrà ´ler  has that meaning in French. The same goes for assist, meaning to attend (assister  in French,  asistir  in Spanish). In other cases, Euro-English is just a naive but incorrect extension of English grammatical rules: many nouns in English that don’t properly pluralise with a final s are merrily used in Euro-English, such as informations and competences. Euro-English also uses words like actor, axis or agent well beyond their narrow range in native English...It could be that whatever native-speakers might consider correct, Euro-English, second language or no, is becoming a dialect fluently spoken by a large group of people who understand each other perfectly well. Such is the case of English in India or South Africa, where a small group of native speakers is dwarfed by a far larger number of second-language speakers. One effect m ay be that this dialect would lose some of the tricky bits of English, such as the future perfect progressive (We will have been working) that aren’t strictly necessary. (Johnson, English Becomes Esperanto. The Economist, April 23, 2016) Euro-English as a Lingua Franca - Tramp . . . could be the first English-language glossy magazine aimed at people who speak Euro-English as a second language. (Social Vacuum. The Sunday Times, April 22, 2007)- In the case of English in Europe, there seems little doubt that it will continue to increase its position as the dominant lingua franca. Whether this will result in varieties of European Englishes, or in a single variety of Euro-English being used as a lingua franca can only be determined by further research. The extent to which it is stifling (Gà ¶rlach, 2002:1) other European languages by steadily encroaching on more and more domains also needs to be researched, as do European attitudes toward English, especially the attitudes of the young. (Andy Kirkpatrick, World Englishes: Implications for International Communication and English Language Teaching. Cambridge University Press, 2007) Further Reading AmericanizationDenglish (Denglisch)Global EnglishGlobishNotes on English as a Global LanguageWorld English

Thursday, November 21, 2019

The Effects of shift work on employee's and their family Essay

The Effects of shift work on employee's and their family - Essay Example Why, however, point out the nature of shift work in such detail? When employees work these dramatically difficult hours for the sake of industry, it tends to put constant stress on the household, including the domestic marriage and, when applicable, the children as well. It is important to highlight that shift work not only affects the industrial worker, it also impacts individuals in law enforcement and various other forms of employment. Hence, problems in the home with extended shift working and rotational schedules can be cited as a widespread issue in today’s society. Shift workers and their family members experience significant domestic complications as a direct result of shift work, negatively impacting the quality of life for many households. It is relatively common knowledge that the average person requires six to eight hours of uninterrupted sleep, somewhat consistently, in order to function at their fullest potential. This includes issues of a well-adjusted metabolism, a positive immune response, and even mental health and well-being (Weiten & Lloyd, 2005). Oftentimes, when an individual works long shifts throughout the average workweek, the demands of the household make it virtually impossible to find quality time and relaxation after a difficult work day. In many instances, in households with younger children and increased family obligations, six to eight hours of uninterrupted sleep is next to impossible to achieve. Studies have suggested that sleep deprivation is often linked to the difficulties of adjusting to shift work, with larger health outcomes including depression and increased anxiety (Morris & Maisto, 2005). All of these health-related issues impact the family when tensions run high within the household o r when health matters require attention and medical expenses increase. Businesses, today, put a great deal of demands and stress on their employees as they drive them to assist in building higher productivity

Tuesday, November 19, 2019

Performance Evaluation Assignment Example | Topics and Well Written Essays - 2000 words

Performance Evaluation - Assignment Example (McIness et al cited by Demirag, 1988, p. 258). The use of a single accounting standard - for both performance measurement and tax reporting removes the risk of a more favourable internal valuation becoming damaging evidence in the event of disputes with tax authorities (Baldenius et al, 2003, p. 592). Also, there is no additional administrative overhead and associated costs that may have resulted if the performance reporting was decoupled from tax reporting. Using only profits as the measurement gauge may work if all other factors are equal. However, the business enterprise is a dynamic environment and all factors rarely, if ever, remain equal and a simple reliance on profitability numbers may not prove an adequate measure of performance, even though it would (and should) provide guidance on the financial health of the organization. Watty and Terzioglue (1999, p. 5) cite Kaplan as saying non-financial measures are just as essential and too much emphasis on just financial measures may decrease an organization's long-term viability. Also, Kren (1994, p. 68) assumes that excessive or inappropriate reliance on accounting performance measures would prompt managers to manipulate accounting data. That this pressure exists within the Niessen culture can be inferred from the US marketing manager's manipulation of the transfer pricing. A profit centre model implies that managerial control is decentralized with ultimate responsibility for centre performance residing the business unit manager. However, Niessen Peru is a captive subsidiary company with only one customer: Niessen Apparels, USA, its parent. The present policy excludes any scope for attracting or soliciting orders from other apparel companies who may or may not be competing in the same market space. This would mean that Valencia's responsibilities are limited to operations: production efficiency and cost control. Being a captive subsidiary, Niessen Peru is totally dependant on the parent company to keep its production capacity fully utilized. Any slackening in the order flow will impact the bottom line. Sales are outside Valencia's control and responsibility. Any performance measure that does not compensate for this factor will present a skewed result that can be easily misinterpreted. The subsequent events bear this out as seen by the increase in idling due to the slow down in US sales and the misinterpretation of the Peru operations statement by management members not aware of the behind the scenes price fixing. Another factor that hasn't been taken into account, as it may effect Niessen's satisfaction with subsidiary performance, is cultural distance. In the context of multi-national companies, cultural distance is the difference in the way business is conducted between companies of different cultural backgrounds. Dikova and Witteloostuijn's (2005, p. 24-25) research suggests that there is a significant positive correlation between cultural similarity and the performance of the subsidiary. Also, they cite Anderson, et al (p. 24) arguing against foreign investments for the sole purpose of increasing short-run financial performance although they do qualify the target market as "young" and

Saturday, November 16, 2019

Great expectations - review of three film versions Essay Example for Free

Great expectations review of three film versions Essay In my English lessons I have been reading great expectations as part of my pro 1914-prose study, and have chosen to do my media assignment on film adaptations of the book. I will be comparing and contrasting the three film versions, David Leans 1945 film is the eldest version which is in black and white, the BBC serialisation and the latest BBC film version, and the original novel. I will structure my essay by writing about different areas of the adaptations e. g. soundtrack, first with similarities then differences between the versions. Sequencing: The sequencing of the opening scene of great expectations adaptations are all quite similar except the latest BBC adaptation, the David Lean and BBC serialisation have the same sequencing, book so it is unlike the 2 other film versions. The David Lean film and BBC serialisation have the sequencing almost of the book so tell the story in the same way as Charles Dickens did. While the David lean version is more compact due to time limitations and the BBC serialisations has more detail they both tell the same set of events in the same way. And only differ from the book in the very beginning where they show Pip the central character in the book running across the marshes to the church, where the book starts in the churchyard. The latest BBC version is very different form the book and two other adaptations in its sequencing, it starts with Pip running away from the convict across a wheat field, when the convict catches up with Pip in the graveyard, he asks no questions about his parents or where he lives like the book. It then switches straight to Pip running home across the marshes, when he arrives home events from the second chapter take place when the events of the first havent finished being explained. The rest of the sequences of the opening chapter take place as flashbacks while pips sleeping. Soundtrack: As with the sequencing the sound track for the latest BBC adaptation is very different to the other two versions as it has a different set of sequencing. The David lean version and BBC serialisations soundtrack are quite similar but the advances in technology makes the serialisation far more advanced than the older David lean version. The David Lean version soundtrack starts with the opening of the book being narrated by an older version of Pip as the younger version crosses the marshes. The BBC serialisation soundtrack is similar to the David Lean version as it begins with narration by an older version of pip as he crosses the marshes. And the latest BBC version soundtrack is very different to the other two, as it starts with quiet music and Pips heavy breathing and rustling as he is running away from the convict. The arrival of the convict is very similar in the David Lean version and BBC serialisation soundtrack with the same build up, whistling winds and creaking trees make up a tense atmosphere, which is shattered by the arrival of the Convict. This is very different in the Latest BBC version. The arrival of the Convict in the David Lean version soundtrack is marked by him grabbing Pip and Pip screaming, the convict then threatens Pip in the following dialogue. Then the convict turns him upside down a lot of rustling and jingling from the convicts chain on his leg. The convict then demands items from Pip in the following dialogue while eating an apple and breathing heavily. At the end of the scene where Pip is running home across the marshes, the whistling winds from the graveyard are heard again. The arrival of the Convict in BBC serialisation soundtrack is different to the David Lean version you hear Pip trip and as he gets he catches sight of the convict and takes a surprised breath. The convict then moves toward him you can hear the chain on his leg jingle with every step he takes, he then talks to Pip. He shakes Pip lots of jingling and grunting, when he resumes dialogue with Pip he is eating a piece of bread. Just before the end of the scene the convict threats Pip speaking in a whisper, then walks of to bouncy music with his chain jingling. The Convict is introduced in the latest BBC version soundtrack by Pip falling with a thud, trying to hide breathing deeply. The Convict catches up breathing heavily and his chain jingling with his footsteps, as the Convict finds Pip, Pip lets out a scream then the convict says a short amount of dialogue. The David Lean and BBC serialisation soundtracks are quite similar but the Serialisation has the advantage of longer running time and detail and better technology, the only difference is the whistling wind at the end of the scene in the David Lean versions apposed to the bouncy music of the convicts departure in the BBC serialisation. The latest BBC version soundtrack is a far shorter and more condensed in the opening scene than the other two adaptations. Also large amounts of dialogue are missed out, even thought it befits from the best technology and methods out of the three adaptations it has the shortest and in my opinion worst soundtrack. Meise en scene: Meise en scene is French for what you can see such as characters, props and scenery. The main way to see the difference in the interpretation of the book in the adaptations is by what and how they present characters and locations on screen. As with the sequencing and sound tracking the David Lean version and BBC serialisation are very similar with few differences although the David Lean version is in black and white and the latest BBC version is very different to both of them. The David Lean version starts with the 1st page of Great Expectations opening then the rest of the pages blowing over. The BBC serialisation opens with some flowers on the book cover of Great Expectations wilting away, it is different to the David Lean opening but is clearly influenced by it. The latest BBC films different sequencing means different images appearing on screen at different time compared to the other two adaptations. It opens with Pip running through a golden wheat field, looking back over his shoulder, his face is dirty and his clothes are hard worn showing that he is a person of lower class in society. This is very different to the other two versions, which show the name of the film/book before the film begins. While the latest BBC version starts in the thick of the story. The appearance of the Convict is very similar in all three versions, which hold true to the book description A fearful man, all in course grey, with a great iron on his leg. The David Lean version while holding true to the book description but makes the Convict more frightening to the audience than the other two versions, as it is limited to black and white to make an impact. The BBC serialisation shows the convict more as a worn out exhausted figure that is more likely to make audiences fell sorry for him than be frightened. He is truer to the description laid down in the book than the other to versions down the blackened face and rag tied around his head. The Convict in the latest BBC version is a cross between the two other versions he is more frightening in appearance than the BBC serialisation Convict, but less true to the books description and more detailed than the David Lean versions Convict. Conclusion: After watching and reviewing all three-film adaptations, I have decided in my opinion that the BBC serialisation is the best adaptation of the book. Because of the level of detail that tells the story as well and in the same fashion that made the book such a large success, I find it an excellent alternative or compliment to reading the novel.

Thursday, November 14, 2019

The Pros and Cons of Language Translation :: Pro Con Essays

To answer the question above we first have to define what is actually meant by translation before we are able to think about the limits and advantages of translation. Translation can be described as an expression of a sense from one language to another as well as a transmission of a written or spoken language into another. Translation is since the beginning of human culture an important item of understanding between different countries. So the â€Å"Stone of Rosette† made it possible to decipher the ancient Egypt language. But here we already see the limits of translation. We never will be able to understand all their feelings. Later on, the translations of the old Greek and Latin authors have influenced all western Europe countries and have let to the grandiose works of Shakespeare for example. Here we see the great advantage translations have brought to all Europe. As the statement in the title says, translation offers us the experience and attitudes of another culture or mentality. When for example reading books from typically English authors like Agatha Christie or George Orwell in German or any other language, we learn something about the culture or mentality, because the good description as well as the feeling of being in Britain at the present time, makes this possible. From this we come to a point which is even more important, the transport of culture and understanding between peoples. A good example for this is the book â€Å"Uncle Toms Hut† which had enforced the fight against slavery world wide but was hardly able to cause political influence. This shows again the limits of translation. On the other side we can not imagine a world without the translation of literary master pieces from all countries, mentioned only the great Russian, German, English and French authors red all over the world. Here we see the problems and limits of translation very closely. A good translation not only transports the sense but also the choice of words and the way of expressing. Especially for translations of high standing literature the translator should be home in both languages. The translator often finds his limit with poems. An other example to show the limits of translation are technical items, which were produced in China or Korea. As we do not speak any Chinese or Korean we are not able to understand what we should do before the first use.

Monday, November 11, 2019

Chemistry Questionnaire Essay

What is meant by the term cis-trans isomerism? How many cis-trans isomers are present in Structure I? Draw any 2 possible cis-trans isomers. (iii) State the physical state of this lipid at room temperature. Explain your answer. [9] (b) Suggest a possible identity for each of the organic compounds A-E below. Explain your reasoning and write balanced equations for the reactions involved where possible. i) A, C11H14O2 is a neutral compound. Hydrolysis of A gives B, C7H6O2 which is a white precipitate and C, C4H10O which does not decolourise acidified potassium manganate(VII) on heating. (ii) D, C4H10O2 reacts with 2 moles of sodium metal, but not with solid sodium carbonate. On boiling under reflux with aqueous potassium manganate(VII), D gives a compound, E, C4H6O3. E reacts with alkaline aqueous iodine to give a yellow precipitate and evolves carbon dioxide when solid sodium carbonate is added. Draw structural formulae of the products of the reactions between glutamic acid and I aqueous NaOH II aqueous HCl (ii) Draw the structural formula of a dipeptide formed between glutamic acid and phenylalanine, showing the ionic form in which it would exist at pH 10. [4] [Total: 20] 5 3 (a) Iron(III) chloride is a dark brown solid which dissolves in water to give an acidic solution. This solution is used to etch, i. e. dissolve, unwanted copper from printed circuit boards. When a copper-coated printed circuit board is immersed in aqueous iron(III) chloride, the solution turns greenish blue. i) Explain, with the aid of an equation, why aqueous iron(III) chloride is acidic. (ii) Use the Data Booklet to explain why iron(III) chloride etches copper. Give a relevant equation to explain the greenish blue solution observed. (iii) Suggest what happens to the overall E0 value if the thickness of the copper coating is increased. Anhydrous aluminium chloride behaves similarly as anhydrous iron(III) chloride in that they sublime readily when heated. When 1. 56 g of aluminium chloride was placed in an evacuated vessel of volume 1. 00 dm3 at 1800C, the pressure produced was 32. kPa. (i) Calculate the apparent relative molecular mass of the aluminium chloride under the stated conditions. (ii) In the vapour phase, aluminium chloride partially exists as a dimer. Using your answer obtained for b(i), calculate the percentage of the dimer under the stated conditions. (iii) Suggest a reason why the dimerisation process of aluminium chloride is exothermic. 6 (iv) Predict, giving a reason in each case, the effect on the proportion of dimer in the equilibrium mixture if I the pressure is lowered, II the temperature is lowered. MgO(s) + CO2(g) ?H? = +117 kJ mol-1; ?S? = +175 J mol-1 K-1 8 (i) Why does the entropy increase when magnesium carbonate decomposes? (ii) Calculate the standard Gibbs free energy change, ? G? , for the decomposition of magnesium carbonate. Comment on the spontaneity of the decomposition of magnesium carbonate at room temperature. (iii) Assuming that ? H? and ? S? for the reaction are independent of temperature, calculate the temperature at which the decomposition reaction becomes feasible. (iv) Compare the ease of thermal decomposition of magnesium carbonate with barium carbonate. [8] Turn over 4 (d) Suggest a simple chemical test to distinguish between each pair of compounds. For each test, give reagents and conditions, and state what would be seen with each compound. The dissociation reactions and Ka values of carbonic acid are given below. H2CO3 HCO3- + H+ Ka1 = 4. 2 x 10-7 mol dm-3 HCO3- CO32 – + H+ Ka2 = 4. 8 x 10-11 mol dm-3 0. 10 mol dm-3 aqueous NaOH is added slowly to 20. 0 cm3 of carbonic acid and the change in pH is followed and shown below. pH x x B x A x x 10 20 30 40 10 Vol of aqueous NaOH added / cm3 (i) Calculate the initial pH of the carbonic acid, stating any assumptions you make. (ii) Calculate the pH at the first equivalence point, A. (iii) What is the pH at point B? Give a reason for your answer. [6] [Turn over 5 (b) Maintenance of pH is vital to the cells of all living organisms because enzyme activity is influenced by pH. For instance, protection from harmful pH change in the blood plasma is provided by the hydrogencarbonate/carbonic acid system (HCO3-/H2CO3). At 370C, the temperature of the human body, pH of blood plasma is 7. 4. i) Explain, with relevant equations, how the hydrogencarbonate/carbonic acid system regul ates the pH of blood plasma. (ii) Calculate the ratio of [HCO3-]/[H2CO3] for maintaining the optimum pH of blood plasma. [4] (c) Describe two differences in physical properties between transition metals and a s-block metal such as magnesium, suggesting reasons for these differences based on their atomic structures. [3] 11 (d) The oxidation of manganese(IV) oxide in alkaline solution in air produces green manganate(VI) ion, MnO42-. When manganate(VI) is added to a dilute acid, a purple solution and dark brown solid manganese(IV) oxide reforms.

Saturday, November 9, 2019

Water shortage may be next cause of world war

While much attention and debate have been correctly focused on the impending planet-wide oil shortage, a far greater calamity awaits us as the reality of the looming global water crisis becomes more apparent. It is not unreasonable to wonder whether the next world war will be fought over oil or water.No resource on Earth is more precious than water. While ongoing events draw our attention to oil, we ignore what will become the most serious resource issue in this century – the international water shortage. The reports that nearly a third of the world’s population lacks clean water for personal daily use and estimates that by 2025 that number will grow to half of the world’s population. A number of world leaders have even suggested that the next world war could be sparked by water disputes.In places as different as the American west, the Middle East, Northern Africa, and China the problem of diminishing water supplies is becoming steadily more serious and more dang erous. The World Bank has reported that as many as 80 countries now have water shortages that threaten their economies as well as their citizens’ health, while 40 percent of the world’s population have no access to clean water and sanitation.In addition, more than a dozen nations receive most of their water from rivers that cross borders of neighbouring countries viewed as hostile. As readily as people and countries ï ¬ ght over control of oil, one can only imagine what it will be like when our precious life source of water is no longer available in sufficient quantities.According to Frank Rijsberman, the director of the International Water Management Institute, â€Å"Globally, water usage has increased six times in the past 100 years and will double again by 2050, driven mainly by irrigation and demands of agriculture.†The consequences of this increase in demand will be widespread scarcity and rapidly increasing water prices. As described in a report issued l ast August by WWF, the global conservation organization, rather than being simply a problem effecting poor and undeveloped countries, the â€Å"combination of climate change and drought and loss of wetlands that store water, along with poorly thought out water infrastructure and resources management, is making this (water) crisis truly global.†In the Middle East, Israelis and Palestinians are ï ¬ ghting over shrinking water resources. In China & India more than 400 of 600 towns & nearby cities are suffering water shortages and in Peru, as around the world, mountain glaciers are in retreat, taking with them vast stores of water that grow crops, generate electricity and sustain communities.â€Å"The situation will only be exacerbated as climate change is predicted to bring lower rainfall, increased evaporation and changed patterns of snow melting.†So what is to be done about this imminent case of water insecurity? The most important ï ¬ rst step is to develop a bette r method of agricultural irrigation. Presently 70 percent of all water use is agricultural, with 60 percent of that water being wasted, primarily through seepage and evaporation. Other strategies to address this growing global water problem include: water conservation, more desalination plants, slowing population growth, reducing pollution, and simply better managing the supply and demand of our most precious resource.Ultimately, there will be no remedy for this seemingly intractable problem unless and until truly sustainable practices of water conservation are undertaken at the personal, national and global level. If we fail to do this, and don’t learn to conserve and cooperate, the war(s) for control of the oil in the Middle East will appear mere picnics by comparison.And in addition to the already existing â€Å"No Blood for Oil† protest signs, our  newest antiwar protesters will be carrying signs saying, â€Å"No War for Water.†

Thursday, November 7, 2019

Managing a business A senior managers role in material management and management of the external environment

Managing a business A senior managers role in material management and management of the external environment Managing a business comes with its own challenges. Senior managers in business organizations must put in place appropriate strategies to ensure that the business runs smoothly without any internal shocks, and also be aware of relevant externalities that can substantially affect their business. Advertising We will write a custom essay sample on Managing a business: A senior managers role in material management and management of the external environment specifically for you for only $16.05 $11/page Learn More To achieve this, there are serious decisions to be made, precautions to be taken, actions to be taken to counter certain externalities, etc. This paper explores the role of a senior manager in ensuring that the materials of a business are carefully managed and also suggests ways in which external business shocks can be managed. As mentioned above, senior managers have a key role to play in ensuring that their business runs smoothly. One of the key things that a manager should be conscious of is the status of materials in the organization. This is especially the case with businesses in the manufacturing industry. The importance of monitoring materials is therefore very important in such a business, if the business is to make any profits. A senior manager should ensure that he/she works closely with the managers responsible for management of materials to keep record of the status of materials and ensure that appropriate actions are taken as and when required. It is of essence that store keepers report to the senior manager in a timely manner so that appropriate actions can be taken. This, therefore, calls for appropriate controls initiated by senior management in the business organization to ensure that such reports are generated as and when required. Information such as the turnover of materials, materials left in the store, materials used per day, etc, should be availed to senior managers at critical times to give room for decisi on making (Sanders, 2006, p. 45). With proper material management by senior managers, the success of a business is guaranteed. Another important thing in the management of a business is the management of the external environment of a business. A senior business manager should ensure that he/she is informed of the status and/or changes in the industry in which his/her business operate. A senior manager should especially have a good understanding of the activities that the competitors of the business may be undertaking in order to gain a competitive edge (Sanders, 2006, p. 37). Advertising Looking for essay on business economics? Let's see if we can help you! Get your first paper with 15% OFF Learn More This is because a competitive edge on the part of competitors means that the business of the senior manager will be losing out on its market share. Additionally, a senior business manager should ensure that he/she gets information on any industrial shocks as ea rly as possible in order to make relevant decisions. This will ensure that the business is not affected badly by such shocks. For instance, in case the industry in which the business is operating will be experiencing shocks due to power outages, the senior manager should be aware in order to take remedial actions that will mitigate the effect that the shock will have on the business. In conclusion, it can be confidently argued that information is the key driver of business success. Whether a business realizes supernormal profits or incurs crippling losses may be determined by the kind of controls that a business organization has put in place to ensure that its senior managers get relevant information in a timely manner. The senior managers therefore have a responsibility to ensure that these controls are working, and also ensure that follow-ups are made on any loophole in the relay of relevant information.

Tuesday, November 5, 2019

30 Idioms About Common Shapes

30 Idioms About Common Shapes 30 Idioms About Common Shapes 30 Idioms About Common Shapes By Mark Nichol Figurative references to circles, squares, and triangles turn up in a variety of familiar expressions. Here’s a list of many of those idioms and their meanings. 1. To be a square peg in a round hole is to be someone who doesn’t fit in a particular environment, or in certain circumstances. 2. To go back to square one is to start over again because of a setback or an impasse. 3. The expression â€Å"Be there, or be square† alludes to often-lighthearted pressure to attend an event or suffer the consequences of being considered conventional and uninteresting. 4–6. To call something square, square something with someone, or square accounts is to agree with another party that neither party owes anything to the other one. 7. To circle around is to move in a circular motion to engage in reconnaissance or to figuratively evaluate a situation. 8. A circular argument is one in which the proposition is assumed to be true. 9. To come (or go) full circle is to figuratively return to one’s starting point. 10. Someone who could fight a circle saw is so tough that the thought of sparring with a deadly power tool does not faze him or her. 11. To say that something doesn’t cut any squares with one means that one refuses to be influenced. 12. To be fair and square is to treat everyone impartially. 13. To look someone square in the eye is to do so directly, indicating honesty. 14. A love, or eternal, triangle is a circumstance in which two people are in love with the same person. 15. To move in the same circles with someone is to have similar tastes and frequent the same locations. 16. Something on the square is done fairly, honestly, and openly. 17. To be out of square is to not be in agreement. 18. To run circles around (or run rings around) someone is to figuratively outcompete him or her to the extent that the other person seems to be standing still. 19. To run around in circles is to figuratively expend much effort with little result because of poor organization or planning. 20. A square answer is an honest one. 21. To square away is to rectify or put in order. 22. A square deal is a fair deal. 23. A square meal is a complete, nutritious set of food servings. â€Å"Three square meals† (often abbreviated to â€Å"three squares†) refers to the traditional daily schedule of breakfast, lunch, and dinner (or supper). 24. To square off is to prepare to fight or compete. 25. To square up is to settle or reconcile. It also means to confront someone or something courageously. 26. To square one’s shoulders is to literally straighten one’s shoulders before undertaking a difficult task or to figuratively prepare oneself for an effort. 27. To attempt to square the circle is to try to do the impossible. 28. To square something with someone means to obtain approval or permission 29. To speak or talk in circles is to discuss an issue or problem repetitively with no progress. 30. A vicious circle (or vicious cycle) is one in which solutions create new problems. Want to improve your English in five minutes a day? Get a subscription and start receiving our writing tips and exercises daily! Keep learning! Browse the Expressions category, check our popular posts, or choose a related post below:English Grammar 101: Verb MoodPersonification vs. Anthropomorphism

Saturday, November 2, 2019

Investment Appraisal Techniques Essay Example | Topics and Well Written Essays - 1250 words

Investment Appraisal Techniques - Essay Example Some of the investment appraisal techniques used range from Net Present Value (NPV), Accounting Rate of Return (ARR), Internal Rate of Return (ARR) and Payback Period. Net Present Value (NPV) As one of the investment appraisal techniques, net present value (NPV) method ensures that the value of all the expected future cash flows is calculated into the present values (Droms, & Wright, 2010). More significantly, the net present value (NPV) method takes into consideration the difference that arises between the present value of the expected cash inflows of a project and the present value of the expected cash outflows that the project will yield in the future (Crosson & Needles, 2011). This is essential in the determination of whether or not the project is viable in the present condition if the projected will yield the projected cash flow in the future (Moyer, McGuigan & Kretlow, 2008). Calculations are done using the discount rate of the cost of capital that is determined depending on co nsiderations of the future projected risk of the project (Hastings, 2009). More so, the use of the net present value (NPV) method in capital budgeting is necessary because it analyzes the profitability level of the intended project (Mowen, Hansen & Heitger, 2012). Above all, use of net present value (NPV) method in capital budgeting analysis is critical because it is more sensitive as compared to other method because it relies on the future cash inflows that the project is expected to yield (Duenas, 2006). Net Present Value (NPV) method YEAR 0 1 2 3 4 TOTAL Initial Outlay (0) (300,000) (300,000) Sales revenue - - 350,000 390,000 410,000 1,150,000 Materials and components - (50,000) (65,000) (65,000) (50,000) (230,000) Salaries and Wages - (70,000) (80,000) (85,000) (85,000) (320,000) Depreciation - (45,000) (45,000) (45,000) (45,000) (180,000) Advertising - (25,000) (25,000) (25,000) (25,000) (100,000) Equipment disposal 120,000 120,000 Net cash flow (0) (490,000) 145,000 170,000 32 5,000 150,000 Discounted factor (15%) 1.0 0.8696 0.7561 0.6575 0.5718 Discounted cash flows (0) (426104) 109,634.50 111,775 185,835 (18,859.5) Overheads are not taken into account as expenses because it is not directly related with the project. More so, the overheads costs are related with the companies head office function. Accounting Rate of Return (ARR) Another investment appraisal technique that is used to estimate the expected rate of return of anticipated investment project is the accounting rate of return (ARR). More significantly, the use of the accounting rate of return (ARR) gives a more rapid way of estimating the expected net profits as a basis for comparing several different expected projects to be undertaken by a company (Siegel, Shim, & Hartman, 1998).   In addition, the accounting rate of return (ARR), takes an estimate of the returns that the expected project will yield during its entire useful life. As compared to the payback period method, the accounting rate of return (ARR) is rational as it considers the distribution of profits and not only the period the project is expected to take to get back the original amount of investment in the project (Brigham & Houston, 2009). One weakness of the accounting